This post contains Naruto's spoilers.
summation
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Sasuke vs. Neji would have been the best chunin test battle.
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NEJI would have defeated Sasuke in the Chunin test because of BYAKUGAN.
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The role of Neji was more important, but it was darker by Naruto and Sasuke.
Sasuke uchiha is a severe person from its objection Naruto series. He was introduced at the beginning of the story and could beat fans in a short time. Sasuke was a genius I learned at an amazing speed and was praised and admired by his classmates.
As Sasuke continued to travel, he faced many amazing fighters that led him to limit, and they helped him better. Because there are many characters, Kishimoto had a hard time determining who would fight. Sometimes Kishimoto's choice was strange, and probably robbed some of the biggest fights.

relevant
Naruto: The relationship between Naruto and Sakura explained
Naruto and Sakura had a very complicated relationship.
Sasuke vs. Neji would have been the best fight in the Chunin test.
Sasuke and NEJI met before the Chunin test. Until that moment, Team 7 seemed to be cut than the rest in terms of strength. But other participants soon showed that they were not stupid. Rock Lee was the first humble team 7 with Taijutsu technology.
As the test proceeded, those who passed the second stage had to fight each other in the preliminary. In the first round, Sasuke fought against Yori Akadō in Ottogaku. Despite the fact that Sasuke could have some difficulties, it was turned out to be a direct fight as Uchiha and Victor. Meanwhile, Neji had to fight Hinata in the preliminary. The former dominated the battle in Get-GO and even humiliated her.
After their victory, Sasuke and Neji were selected as one of the finalists. Kishimoto decided that Sasuke decided to fight Gaara. Nezy, on the other hand, was chosen to fight Naruto. Neji and Naruto argued for prospective people because Hyuga abused Hinata. Naruto came in and criticized Neji's approach. So it was reasonable for them to fight each other. Another reason why Kishimoto decided to fight Neji is that only the latter can bypass a soft fist.
Who will win between Neji and Sasuke?
NEJI would have eliminated Sasuke in the first part
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NEJI better controlled his dojutsuu
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Neji was physically stronger
The answer depends on the two fights. If you were during the Chunin test, NEJI would have wiped the floor with Sasuke. The latter was a talented fighter, but NEJI had much better control of his byakugan than Sasuke did. In addition, Neji was able to use a soft fist, and with him, he was able to stop the chakra's flow in the body of another person. If NEJI has attacked Sasuke several times, the latter Tenketsu would have been blocked. And the possibility of survival of Uchiha would have been zero.
Throughout this time, I was called a genius. So I can't lose it. –Neji hyuuga
As mentioned earlier, Naruto was selected by Kishimoto. Because he was the only person who could bypass the effect with the help of Kurama.
At the start of part 2, the fight between Neji and Sasuke would have been somewhat interesting. At that time, Sasuke learned many new technologies and was stronger than Naruto. But Neji would have been too far behind it. After all, he was the only member of Konoha 11 who achieved Jonin's class.
Neji's role had to be bigger
When the story was over, Kishimoto forgot many characters and completely worked. They were rarely given the screen time, and the fans had to wait for several sheets to see them. NEJI was one of Kishimoto's better use. In the first half of the story, he was congratulated as a genius who could go to the toe as the biggest name, but in the second half, the situation changed.
Despite the only Jonin of Konoha 11, NEJI was rarely received because Kishimoto was transformed by Naruto and Sasuke. Neji died in the fourth great ninja war, and Neji had a bad situation. He was killed in bizarre and very overwhelming reasons. Kishimoto would have participated more in the story. If he was still alive, he would have been a perfect teacher to Boruto. Unfortunately, it will never go.

Naruto
- Release date
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October 2, 2002
- network
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Adult